全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

中国耕地土壤相对湿度时空分异   总被引：4，自引：1，他引：3  

潘汉雄  朱国锋  张昱  郭慧文  雍磊磊  万巧卓  马惠莹  李森 《地理学报》2019,74(1):117-130

以全国653个农业气象站1993-2013年耕地的土壤相对湿度数据为基础,运用地统计方法,分析中国耕地土壤相对湿度时空分异特征与规律。结果表明：自1993年以来全国耕地的土壤相对湿度呈现波动上升趋势。全国耕地的土壤相对湿度普遍大于60%,分布区域自4月中旬开始随夏季风推移不断向北向西扩大,自10月下旬开始向东、南方向缩小。耕地土壤相对湿度值随土壤深度的增加而增加。年际尺度上,耕地的土壤相对湿度在夏秋季上升速度最快,变化幅度随土层深度增加而变小。土壤相对湿度与降水量存在较强的正相关关系,与潜在蒸发量、气温普遍存在较强的负相关关系。土壤相对湿度与各气象要素的相关性随深度加深而减弱。春、夏、秋季气象因素对旱地土壤相对湿度影响较大,冬季气象因素对水田影响更大。  相似文献   

基于手机数据的北京市城市与近郊交互模式挖掘     

彭卉  杜云艳  易嘉伟  刘张  王会蒙 《地球信息科学学报》2019,21(1):97-106

在城镇化进程中,城市与近郊之间通过职住、货运、游憩等活动产生越来越紧密的交互联系,对于这些交互联系的准确识别和定量刻画,是理解城乡空间关系的重要手段,也能为城市的资源有效配置与合理规划提供重要的现状信息。本文通过对全北京在一日之内的手机信令数据所反映的人群移动轨迹的深入分析,融合城市的POI信息形成顾及人类活动时空信息的空间交互类型推断。以北京市为例,对城市中心与近郊之间远距离的强交互进行定性、定量和定位的探索。本文发现了北京市多尺度下空间交互模式和距离衰减规律,判断了城乡异常交互类型,对比了城乡之间和城市内部的交互模式的异同,以及基于交互类型视角提取了城乡异常交互的空间特征。研究认为,基于手机信令数据,利用停留点提取和高斯核密度估计的空间交互类型推断有效地发现了北京市周末的远距离出行类型特点,提取了其空间交互强度和空间特征,揭示了基于人类活动的北京市周末城乡交互模式。  相似文献   

北大巴山早古生代辉绿岩地球化学特征及其地质意义     

张方毅  赖绍聪  秦江锋  朱韧之  杨航  朱毓 《岩石矿物学杂志》2020,39(1):35-46

对南秦岭北大巴山地区广泛分布的一套基性岩墙群中的辉绿岩进行采样,并进行了锆石U-Pb年代学、全岩地球化学分析。结果显示,岩石形成年龄为435~433 Ma,为早志留世晚期岩浆活动产物。这些辉绿岩具低硅、高碱、高钛的碱性岩特征。岩石微量及稀土元素具板内玄武岩特征,轻稀土元素相对富集,轻重稀土元素分异明显,富集不相容元素Ba、Nb、Ta,而K、Y、Yb相对亏损;K及Rb的负异常表明岩石源区残留角闪石或金云母,部分熔融模拟结果显示岩石起源于尖晶石角闪石岩高程度部分熔融。综合地球化学特征及前人研究结果,认为北大巴山地区在早古生代处于大规模伸展裂陷背景下,岩石圈的拉张诱发了低熔点的交代岩石圈地幔熔融,进而形成了这条碱性岩浆带。  相似文献   

Undrained lower bound solutions for end bearing capacity of shallow circular piles in non-homogeneous and anisotropic clays     

Boonchai Ukritchon  Suraparb Keawsawasvong 《国际地质力学数值与分析法杂志》2020,44(5):596-632

The undrained bearing capacity of shallow circular piles in non-homogeneous and anisotropic clay is investigated by the lower bound (LB) finite element limit analysis (FELA) under two-dimensional (2D) axisymmetric condition using second-order cone programming, and the new solution of the problem is presented. Modified from the isotropic von Mises yield criterion, a cross-anisotropic undrained strength criterion of clays under the axisymmetric state of stress requiring three input shear strengths in triaxial compression, direct simple shear, and triaxial extension is employed in the 2D axisymmetric LB FELA. Parametric studies on the effects of pile embedment ratio, dimensionless strength gradient, anisotropic strength ratio, and pile roughness are investigated extensively, while the predicted failure mechanisms associated with these parameters are discussed and compared. Numerical results of undrained end bearing capacity of shallow circular piles are summarized in the form of design tables that are useful for design practice and represent a new contribution to the field of pile capacity considering the combined effects of undrained strength non-homogeneity and anisotropy.  相似文献   

西藏冈底斯岩带曲水杂岩体锆石LA-ICP-MS U-Pb年龄及其地质意义     

次琼  永忠拉达  阿旺旦增  次仁吉 《沉积与特提斯地质》2020,40(2):116-128

曲水杂岩体位于冈底斯构造-岩浆岩带东段南缘,其岩浆活动与雅鲁藏布江新特提斯洋壳向北俯冲、消减以及印度与欧亚板块碰撞息息相关。本文以曲水县-昌果乡广泛分布的中酸性花岗岩体为研究对象,进行了系统的LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果表明,曲水杂岩体由3期时代和规模不同的花岗质岩体构成,其LA-ICP-MS锆石U-Pb年龄分别为95.2±1.0～88.5±1.0Ma、65.2±0.6Ma和48.5±0.5～43.3±0.7Ma;岩石地球化学研究表明,晚白垩世和古新世花岗岩以中性-中酸性为主,属钙碱性系列,具中铝特征,A/CNK比值小于1.1,属于I型花岗岩,是玄武质下地壳部分熔融产物,指示其形成于特提斯洋壳俯冲过程的岛弧构造环境。始新世花岗岩以高钾钙碱性系列为主,并出现钾玄岩系列,具偏铝-过铝质特征,指示岩浆上侵过程中遭受了不同程度的地壳物质混染,其形成于印度-欧亚板块强烈碰撞的构造环境。  相似文献   

Crack nucleation in saturated porous media     

Luc Dormieux  Eric Lemarchand  Thomas Carlioz  Laurent Jeannin 《国际地质力学数值与分析法杂志》2020,44(5):553-574

Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.  相似文献   

黄河干流头道拐河段凌汛期小流量过程变化及其影响因素研究     

全栋  李超  路新川  史小红  杨朝霞 《冰川冻土》2020,42(2):620-628

黄河干流内蒙古段河道冬季流凌封河期， 河道水量除一部分转化为冰量外， 很大一部分转化为槽蓄水量而贮存在河道中， 导致下游头道拐河段出现小流量过程， 上游河道流量转化为槽蓄水量和贮存的冰量越大， 小流量持续时间越长， 开河期发生凌汛洪水风险越高。通过对1998 - 2016年头道拐站凌讯期流量变化过程分析， 重新界定了小流量上限阈值为330 m³·s^-1， 并且以此值为标准进行小流量过程研究， 分别采用R/S极差分析法、 Fourier变换分析法对近年来小流量过程变化特征进行分析； 结合非线性概率Logit模型和Probit模型对小流量过程的影响因素进行讨论。结果表明： 小流量持续天数变化呈现缩短趋势； 同时， 小流量过程与上游相对来水之间变化关系显著且过程同步， 而滞后于河道槽蓄水量变化过程； 通过Logit模型和Probit模型分析各影响因素变化时相应小流量持续时间变化的响应概率大小， 明确河道冰流量是小流量过程第一影响因素， 气温条件是小流量过程的决定因素， 首封位置和相对来水量是小流量过程重要影响因素。  相似文献   

Adding the missing third and fourth dimensions to trajectory analysis in carbonate systems     

Philipp Tesch  Robert S. Reece  James R. Markello  Juan Carlos Laya  Michael C. Pope 《Basin Research》2020,32(2):388-401

We developed a seismic geomorphology-based procedure to enhance traditional trajectory analysis with the ability to visualize and quantify lateral variability along carbonate prograding-margin types (ramps and rimmed shelves) in 3D and 4D. This quantitative approach analysed the shelf break geometric evolution of the Oligo-Miocene carbonate clinoform system in the Browse Basin and delineated the feedback between antecedent topography and carbonate system response as controlling factor on shelf break rugosity. Our geometrical analysis identified a systematic shift in the large-scale average shelf break strike direction over a transect of 10 km from 62° to 55° in the Oligo-Miocene interval of the Browse Basin, which is likely controlled by far-field allogenic forcing from the Timor Trough collision zone. Plotting of 3D shelf break trajectories represents a convenient way to visualize the lateral variability in shelf break evolution. Shelf break trajectories that indicate contemporaneous along-strike progradation and retrogradation correlate with phases of autogenic slope system re-organization and may be a proxy for morphological stability of the shelf break. Shelf break rugosity and shelf break trajectory rugosity are not inherited parameters and antecedent topography does not dictate long-term differential movement of the shelf margin through successive depositional sequences. The autogenic carbonate system response to antecedent topography smooths high-rugosity areas by filling accommodation and maintains a relatively constant shelf break rugosity of ~150 m. Color-coding of the vertical component in the shelf break trajectory captures the creation and filling of accommodation, and highlights areas of the transect that are likely to yield inconsistent 2D sequence stratigraphic interpretations.  相似文献   

Normal fault growth influenced by basement fabrics: The importance of preferential nucleation from pre‐existing structures     

Luca Collanega  Katherine Siuda  Christopher A.‐L. Jackson  Rebecca E. Bell  Alexander J. Coleman  Antje Lenhart  Craig Magee  Anna Breda 《Basin Research》2019,31(4):659-687

Reactivation of pre‐existing intra‐basement structures can influence the evolution of rift basins, yet the detailed kinematic relationship between these structures and overlying rift‐related faults remains poorly understood. Understanding the kinematic as well as geometric relationship between intra‐basement structures and rift‐related fault networks is important, with the extension direction in many rifted provinces typically thought to lie normal to fault strike. We here investigate this problem using a borehole‐constrained, 3D seismic reflection dataset from the Taranaki Basin, offshore New Zealand. Excellent imaging of intra‐basement structures and a relatively weakly deformed, stratigraphically simple sedimentary cover allow us to: (a) identify a range of interaction styles between intra‐basement structures and overlying, Plio‐Pleistocene rift‐related normal faults; and (b) examine the cover fault kinematics associated with each interaction style. Some of the normal faults parallel and are physically connected to intra‐basement reflections, which are interpreted as mylonitic reverse faults formed during Mesozoic subduction and basement terrane accretion. These geometric relationships indicate pre‐existing intra‐basement structures locally controlled the position and attitude of Plio‐Pleistocene rift‐related normal faults. However, through detailed 3D kinematic analysis of selected normal faults, we show that: (a) normal faults only nucleated above intra‐basement structures that experienced late Miocene compressional reactivation, (b) despite playing an important role during subsequent rifting, intra‐basement structures have not been significantly extensionally reactivated, and (c) preferential nucleation and propagation of normal faults within late Miocene reverse faults and folds appears to be the key genetic relationship between contractionally reactivated intra‐basement structures and rift‐related normal faults. Our analysis shows that km‐scale, intra‐basement structures can control the nucleation and development of newly formed, rift‐related normal faults, most likely due to a local perturbation of the regional stress field. Because of this, simply inverting fault strike for causal extension direction may be incorrect, especially in provinces where pre‐existing, intra‐basement structures occur. We also show that a detailed kinematic analysis is key to deciphering the temporal as well as simply the spatial or geometric relationship between structures developed at multiple structural levels.  相似文献